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Material Recycle Index calculator.

Quantify the fraction of all process materials that are recovered and recycled. MRI captures the circular economy performance of an entire process — across reagents, solvents, catalysts, and auxiliaries — in a single percentage. Results update live as you type, and every session stays in your browser, never on a server.

Principle 1 guide
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What is the Material Recycle Index — and why does it matter?

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The Material Recycle Index (MRI) measures the fraction of all materials used in a chemical process that are successfully recovered and recycled, expressed as a percentage. Unlike the E-factor, which quantifies waste generated, or the Solvent Recycle Index (SRI), which is limited to solvents, MRI provides a holistic, process-wide view of circular material use — capturing reagents, solvents, catalysts, auxiliaries, and workup materials together.

A high MRI reflects a genuinely circular process: materials are not simply used once and discarded, but are recovered, returned to the process, and their embedded energy and cost are preserved. This aligns directly with Green Chemistry Principle 1 (Prevent Waste) and supports the broader goals of industrial circular economy.

GoalMaximise the mass fraction of all process materials that are recovered and recycled — an ideal MRI of 100% means all material is returned to the process with zero net consumption.
WhyHigher MRI reduces raw material demand, waste disposal costs, environmental burden, and process operating cost. It is a key metric for moving from linear to circular chemistry.
HowRecover and recycle solvents by distillation or membrane separation; regenerate catalysts; reclaim unreacted reagents; close material loops across process steps.

The formula

$$\text{MRI} (\%) = \frac{m_{\text{recycled}}}{m_{\text{total input}}} \times 100$$
SymbolTermUnits
$\text{MRI}$Material Recycle Index% (0–100%); ideal = 100%
$m_{\text{recycled}}$Total mass of all materials successfully recovered and recycled back into the process or supply chaing (or kg)
$m_{\text{total input}}$Total mass of all materials entering the process (reagents, solvents, catalysts, auxiliaries, workup materials)g (or kg)

"Recycled" means material that is recovered and returned to use — either back into the same process step, to another step, or to an external supply chain. Material sent to incineration, landfill, or waste water treatment is not recycled. The denominator is the total mass of all materials input to the process, not just the waste. A higher MRI is always better.

MRI benchmarks by context

Process typeTypical MRINotes
Highly optimised industrial process60–90%Closed-loop solvent recovery, catalyst regeneration
Pharmaceutical API synthesis10–40%Complex workup, limited solvent recovery, single-use reagents
Undergraduate teaching lab0–15%Minimal recovery; solvents typically disposed
Ideal circular process100%All auxiliary materials recovered; only feedstock atoms consumed

Strengths and limitations

Strengths

  • Captures circular economy performance across the entire material inventory
  • Simple to calculate from lab records; no molecular weights needed
  • Complements E-factor: high MRI directly reduces E-factor waste total
  • Comparable across processes and scales; useful for benchmarking improvements
  • Highlights which material categories have the greatest recovery potential

Limitations

  • Treats all materials equally: 1 g of water = 1 g of expensive chiral catalyst
  • Does not capture the quality or purity of recovered material
  • High MRI for water recovery may mask poor performance for high-impact solvents
  • Does not capture energy consumption, toxicity, or lifecycle impacts
  • Requires experimental data — cannot be calculated at the design stage

MRI in context: complementary green metrics

MetricWhat it measuresIdeal direction
E-FactorMass of all waste per mass of productMinimise (→ 0)
PMITotal material input per mass of productMinimise (→ 1)
SRIFraction of solvents recovered and recycled (%)Maximise (→ 100%)
MRIFraction of all materials recovered and recycled (%)Maximise (→ 100%)
WRRFraction of generated waste that is recovered/recycledMaximise (→ 100%)
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Experiment details

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Process materials

Enter all materials used in the process: reagents, solvents, catalysts, and workup/purification materials. For each entry, enter the total mass used and the mass successfully recovered and recycled. The desired product(s) should not be included here — MRI measures the recycling performance of auxiliary and process materials, not product recovery.

Material name Category Mass used (g) Mass recycled (g) Recycle %
Σ Total input g Σ Total recycled g
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Results

MRI
% recycled
Total Recycled
grams recovered
Total Input
grams used
Not Recycled
grams lost / discarded
MRI scale (higher is better)
0%25%50%75%100% (ideal)

Recycled vs. not recycled by category

Recycled vs. not recycled mass balance

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Detailed breakdown & interpretation

MaterialCategoryMass used (g) Recycled (g)Not recycled (g)Recycle %Visual
Enter materials above to see breakdown.

Interpretation

Enter your process materials above to generate an interpretation.
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Save & load sessions

Sessions are stored in your browser only. No data leaves your device.

No saved sessions yet.
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Export

Export your MRI calculation as a PDF report or CSV data file. PDF opens in a new tab and uses your browser's print function. CSV downloads directly.

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Where can I read more?

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References are sorted alphabetically by first author.

  1. P. T. Anastas and J. C. Warner, Green Chemistry: Theory and Practice, Oxford University Press, 1998. ISBN 978-0-19-850698-0. — Original statement of the 12 Principles; frames waste prevention as Principle 1.
  2. C. Jiménez-González et al., Org. Process Res. Dev., 2011, 15, 912–917. DOI. — Introduces PMI; discusses material efficiency and solvent recycling in pharmaceutical processes.
  3. G. A. Keoleian and I. S. Jawahir, in Treatise on Sustainability Science and Engineering, ed. J. K. Jawahir, Springer, 2013. — Circular economy metrics for chemical processes including material recycle rates.
  4. R. A. Sheldon, Green Chem., 2007, 9, 1273–1283. DOI. — E-factor and complementary green metrics including material recovery.
  5. R. A. Sheldon, Green Chem., 2023, 25, 1704–1728. DOI. — Updated green metrics landscape including material recycling and circular chemistry.
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Contributors

Roles follow the CRediT taxonomy (Contributor Roles Taxonomy), adapted for educational software. Hover a contributor's name for a summary, or a column header for the definition of that role.

Contributor

© 2024– DodecaGreen Project. All rights reserved. · Last updated: 08/06/2026

This portal was built with the assistance of a large language model (Claude, Anthropic), which was used to generate and refine code, articulate and structure contributed ideas within the defined page format, and support iterative design decisions. All scientific content, conceptual frameworks, pedagogical choices, and final outputs were directed, reviewed, and verified by the contributors listed above.

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How do I cite this page?

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If you use this tool in teaching or published work, please cite the DodecaGreen portal as the source.

Reference
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